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51.
Yongqing Li Jiuchuang Yuan Maodu Chen Fengcai Ma Mengtao Sun 《Journal of computational chemistry》2013,34(19):1686-1696
An accurate single‐sheeted double many‐body expansion potential energy surface is reported for the title system. A switching function formalism has been used to warrant the correct behavior at the and dissociation channels involving nitrogen in the ground and first excited states. The topographical features of the novel global potential energy surface are examined in detail, and found to be in good agreement with those calculated directly from the raw ab initio energies, as well as previous calculations available in the literature. The novel surface can be using to treat well the Renner–Teller degeneracy of the and states of . Such a work can both be recommended for dynamics studies of the reaction and as building blocks for constructing the double many‐body expansion potential energy surface of larger nitrogen/hydrogen‐containing systems. In turn, a test theoretical study of the reaction has been carried out with the method of quantum wave packet on the new potential energy surface. Reaction probabilities, integral cross sections, and differential cross sections have been calculated. Threshold exists because of the energy barrier (68.5 meV) along the minimum energy path. On the curve of reaction probability for total angular momentum J = 0, there are two sharp peaks just above threshold. The value of integral cross section increases quickly from zero to maximum with the increase of collision energy, and then stays stable with small oscillations. The differential cross section result shows that the reaction is a typical forward and backward scatter in agreement with experimental measurement result. © 2013 Wiley Periodicals, Inc. 相似文献
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I. V. Nemchinov V. I. Artem'ev V. I. Bergelson V. M. Khazins T. I. Orlova V. A. Rybakov 《Shock Waves》1994,4(1):35-40
A method of possible diagnostics of supersonic flows around a blunt body and its aerodynamic characteristics by means of a thin channel of reduced density emerging in front of the bow shock wave is discussed. The channel was placed parallel to the body axis or inclined to it. Under the conditions of initially uniform pressure the temperature in the channel (the hot spike) is higher than that of the environment. A thin hot spike, which as its limit is infinitely thin, results in the formation of a precursory disturbance in front of the bow shock wave. The length of the precursor is comparable with the characteristic length, that is, the cross section of the blunt body. The hot spike when localized parallel to the body axis and not in line with it yields turning and deviating moments, a lift force was generated even for a symmetric blunt body. Possible applications of this effect are, for example, a change of the trajectory of a small asteroid by means of using the hot spike.This article was processed using Springer-Verlag TEX Shock Waves macro package 1.0 and the AMS fonts, developed by the American Mathematical Society. 相似文献
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Classical problems in integral geometry and geometric probability involve the kinematic measure of congruent segments of fixed length within a convex body in R3. We give this measure from rotational formulae; that is, from isotropic plane sections through a fixed point. From this result we also obtain a new rotational formula for the volume of a convex body; which is proved to be equivalent to the wedge formula for the volume. 相似文献
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生物电阻抗法(BIA)是一种安全非侵入式的、结果可靠有效的人体组成成分(脂肪含量)测量方法。以此为原理,设计了一款便携式无线人体脂肪率测量仪。硬件上,系统以高集成化、低功耗的阻抗测量芯片AD5933为核心,通过蓝牙实现与上位机的无线通信,大大降低了设备的复杂度。软件部分提出一种单频点小阻抗范围的增益系数校准方式,计算量小且容易实现。将新测量仪和欧姆龙体脂仪HBF-358进行对比实验,并作Bland-Altman一致性分析。结果表明,二者的相关系数为0.997。此外,该测量仪还具有易操作、小型化的特点。 相似文献
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Ebrahim Asadi Ahmad R. Farrahi Shahriar J. Fariborz 《Theoretical and Applied Fracture Mechanics》2011,56(2):112-121
The solutions of axisymmetric Volterra type climb and glide edge dislocations are obtained in a layer by means of the Hankel transforms. Utilizing the same procedure, Green’s function solution is obtained for a layer under self-equilibration normal ring traction. The distributed dislocation technique is used to construct integral equations for a system of co-axial annular cracks where the layer is under axisymmetric normal loads. These equations are solved numerically to obtain dislocation density on the cracks surfaces. The results are employed to determine stress intensity factors for annular and penny-shaped cracks and the interaction between two co-axial penny-shaped cracks is studied. Moreover, the stress intensity factors of the interacting cracks are determined such that they can be further used in conjunction with strain energy density (SED) failure criterion to obtain the possible direction of crack initiation that may not be apparent under mixed mode conditions. 相似文献
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The flow field downstream of a bluff body in a typical open channel flow was explored by two-dimensional particle image velocimetry. Measurements are obtained in horizontal planes at the near-bed, mid-depth and near-surface locations downstream of the body up to a streamwise distance of 10D, where D is the width of the body. The dimensionless streamwise defect velocity profile of the wake flow matches well with the data of a previous investigation and does not reflect any dependency on the distance from the bed. However, the nature of development of the recirculation region is found to be different at the three vertical locations. The time-averaged streamline pattern indicates the existence of a unique nodal pattern close to the bed. The variation of the half-width is also found to be affected by the presence of the bed and the free surface. The bed friction arrests the transverse growth of the shear layer, and the free-surface helps to redistribute the turbulent kinetic energy in the streamwise and transverse directions. Swirling strength analysis is carried out to compare the behavior and statistics of the vortex population in the vertical direction. The prevailing magnitude of the swirling strength is found to be different at the three vertical locations. Bed friction assists to dissipate vorticity rapidly, and therefore reduces the probability of appearance of strong vortices close to the bed. 相似文献
59.
钝体绕流的分隔板控制技术研究进展 总被引:1,自引:0,他引:1
钝体是工程中一种常见结构,流体绕过钝体时产生的旋涡脱落易诱发结构振动,进而导致结构破坏.钝体后安装分隔板是一种典型的被动控制技术,分隔板推迟钝体尾流区剪切层之间的相互作用,进而有效改变钝体后旋涡脱落及尾迹特性,延长结构寿命,并且可以利用钝体一分隔板结构进行能量收集.本文全面回顾了利用分隔板进行流动控制和能量收集的研究及... 相似文献
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